Enrichment of Rh,Ru, Ir and Os in Cr spinels from oxidized magmas: Evidence from the Ambae volcano,Vanuatu     

Jung-Woo Park  Ian H. Campbell  Stephen M. Eggins 《Geochimica et cosmochimica acta》2012

Experimental studies, performed under oxidized conditions (fO₂ > QFM + 2, where QFM is quartz–fayalite–magnetite oxygen buffer), have shown that Rh, Ru, Ir and Os are strongly compatible with Cr spinel, whereas empirical studies of Cr spinels from ultramafic–mafic rocks suggest that the experimental results may overestimate the partition coefficients. We report laser-ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) analyses of platinum-group elements (PGE), Au and Re abundances in Cr spinels from the Ambae volcano, Vanuatu (fO₂ = QFM + 2.5), the Jimberlana layered intrusion, western Australia, and the Bushveld complex, South Africa (fO₂ ～ QFM). The results show that Rh and IPGEs (Iridium-group PGE; Ru, Ir, Os) partition strongly into the Cr spinels that crystallized from the oxidized Ambae lavas whereas most of the Cr spinels from the more reduced Jimberlana layered intrusion and the Bushveld complex contain no detectable PGE, Au or Re, with exception of ～10 ppb of Ir in some Jimberlana Cr spinels. In the Ambae Cr spinels, Rh, Ru and, to lesser extent Os, are positively correlated with Fe³⁺, Ni and V. The homogeneous distribution of Rh and IPGEs in LA-ICP-MS time-resolved spectra indicates that these elements are in solid solution in Cr spinels. Pt–Fe alloys occur as inclusions within the Ambae Cr spinels, which indicate that the Ambae melt was saturated with Pt.Our results show that partitioning of Rh, Ru and Ir into Cr spinels increases with increasing oxygen fugacity, which suggests that the high concentrations of these elements in the Ambae Cr spinels are due to the high oxygen fugacity of the host magma. Therefore, Cr spinels may play an important role in controlling the concentrations of Rh and IPGEs during fractional crystallization of oxidized ultramafic–mafic magmas and during partial melting of oxidized arc mantle.  相似文献   

A Neoarchean dismembered ophiolite complex from southern India: Geochemical and geochronological constraints on its suprasubduction origin   总被引：1，自引：0，他引：1  

T. Yellappa  M. SantoshT.R.K. Chetty  Sanghoon KwonChansoo Park  P. NageshD.P. Mohanty  V. Venkatasivappa 《Gondwana Research》2012,21(1):246-265

Ophiolites, the remnants of ancient oceanic lithosphere, have been described from collisional sutures of various ages with only few examples from Archean terranes. Here we report the discovery of a Neoarchean ophiolite suite from the southern margin of the Dharwar Craton in India, tectonically intercalated within a Neoproterozoic suture zone. The metamorphosed and variably dismembered ophiolite suite, exposed around Devanur, comprises altered ultramafic units, websterite, gabbros, mafic dykes, amphibolites, trondhjemites and pegmatites associated with ferruginous metachert. Structural and petrographic studies indicate that the rocks represent a highly sheared and metamorphosed suite emplaced as a thrust sheet. The major and trace element geochemistry of the mafic dykes indicate derivation from basaltic-andesitic magmas with tholeiitic to calc-alkaline characteristics. The rocks display negative Nb anomalies with enrichment of LILE (K, Rb, Ba, Th) and depletion in HFSE (Ti, Nb, Hf, Tb). The tectonic discrimination of these rocks based on various geochemical plots suggests that they were generated in a suprasubduction zone setting. We present new SHRIMP zircon U-Pb data for two trondhjemite samples from this complex, which yield ²³⁸U-²⁰⁶Pb ages of 2528 ± 61 and 2545 ± 56 Ma. The Neoarchean age from the trondhjemites obtained in our study is closely comparable to similar ages obtained in recent studies from magmatic zircons in charnockites and orthogneisses in the area. The suprasubduction zone assemblages and arc magmas suggest a Neoarchean ocean closure along the southern margin of the Dharwar Craton.  相似文献   

Phytoplankton Size and Taxonomic Composition in a Temperate Estuary Influenced by Monsoon     

Yongsik Sin  Bonggil Hyun  Quang-Dung Bach  Sungryull Yang  Chul Park 《Estuaries and Coasts》2012,35(3):839-852

Temporal and spatial variations in phytoplankton in Asan Bay, a temperate estuary under the influence of monsoon, were investigated over an annual cycle (2004). Phytoplankton blooms started in February (>20 μg chl l⁻¹) and continued until April (>13 μg chl l⁻¹) during the dry season, especially in upstream regions. The percentage contribution of large phytoplankton (micro-sized) was high (78–95%) during the blooms, and diatoms such as Skeletonema costatum and Thalassiosira spp. were dominant. The precipitation and freshwater discharge from embankments peaked and supplied nutrients into the bay during the monsoon event, especially in July. Species that favor freshwater, such as Oscillatoria spp. (cyanobacteria), dominated during the monsoon period. The phytoplankton biomass was minimal in this season despite nutrient concentrations that were relatively sufficient (enriched), and this pattern differed from that in tropical estuaries affected by monsoon and in temperate estuaries where phytoplankton respond to nutrient inputs during wet seasons. The flushing time estimated from the salinity was shorter than the doubling time in Asan Bay, which suggests that exports of phytoplankton maximized by high discharge directly from embankments differentiate this bay from other estuaries in temperate and tropical regions. This implies that the change in physical properties, especially in the freshwater discharge rates, has mainly been a regulator of phytoplankton dynamics since the construction of embankments in Asan Bay.  相似文献   

National scale evaluation of groundwater chemistry in Korea coastal aquifers: evidences of seawater intrusion   总被引：3，自引：2，他引：1  

Youngyun Park  Jin-Yong Lee  Jeong-Hee Kim  Sung-Ho Song 《Environmental Earth Sciences》2012,66(3):707-718

Pollution of groundwater by seawater intrusion poses a threat to sustainable agriculture in the coastal areas of Korea. Therefore, seawater intrusion monitoring stations were installed in eastern, western, and southern coastal areas and have been operated since 1998. In this study, groundwater chemistry data obtained from the seawater intrusion monitoring stations during the period from 2007 to 2009 were analyzed and evaluated. Groundwater was classified into fresh (<1,500 μS/cm), brackish (1,500–3,000 μS/cm), and saline (>3,000 μS/cm) according to EC levels. Among groundwater samples (n = 233), 56, 7, and 37% were classified as the fresh, brackish, and saline, respectively. The major dissolved components of the brackish and saline groundwaters were enriched compared with those of the fresh groundwater. The enrichment of Na⁺ and Cl⁻ was especially noticeable due to seawater intrusion. Thus, the brackish and saline groundwaters were classified as Ca–Cl and Na–Cl types, while the fresh groundwater was classified as Na–HCO₃ and Ca–HCO₃ types. The groundwater included in the Na–Cl types indicated the effects of seawater mixing. Ca²⁺, Mg²⁺, Na⁺, K⁺, SO₄ ²⁻, and Br⁻ showed good correlations with Cl⁻ of over r = 0.624. Of these components, the strong correlations of Mg²⁺, SO₄ ²⁻, and Br⁻ with Cl⁻ (r ≥ 0.823) indicated a distinct mixing between fresh groundwater and seawater. The Ca/Cl and HCO₃/Cl ratios of the groundwaters gradually decreased and approached those of seawater. The Mg/Cl, Na/Cl, K/Cl, SO₄/Cl, and Br/Cl ratios of the groundwaters gradually decreased, and were similar to or lower than those of seawater, indicating that Mg²⁺, Na⁺, K⁺, SO₄ ²⁻, and Br⁻, as well as Cl⁻ in the saline groundwater can be enriched by seawater mixing, while Ca²⁺ and HCO₃ ⁻ are mainly released by weathering processes. The influence of seawater intrusion was evaluated using threshold values of Cl⁻ and Br⁻, which were estimated as 80.5 and 0.54 mg/L, respectively. According to these criteria, 41–50% of the groundwaters were affected by seawater mixing.  相似文献   

A pressure-monitoring method to warn CO2 leakage in geological storage sites     

Yong-Chan Park  Dae-Gee Huh  Chan-Hee Park 《Environmental Earth Sciences》2012,67(2):425-433

This paper proposes a pressure-monitoring method to warn any possible CO₂ leakage by monitoring pressure change at the upper layer of storage reservoirs within injection wells. The monitoring method is tested with two problems under various scenarios. With a current pressure detection limit, the proposed pressure-monitoring technique can be widely applicable wherever a permeable upper formation exists above the CO₂ storage reservoir and is effective even in offshore storage sites wherever conventional monitoring methods for onshore sites cannot be applied. Meanwhile, the method is limited to apply during injection and is subject to any possible pressure dampening.  相似文献   

Adsorption of NH<Subscript>4</Subscript> <Superscript>+</Superscript>-N and <Emphasis Type="Italic">E. coli</Emphasis> onto Mg<Superscript>2+</Superscript>-modified zeolites     

Sang-Woo An  Young-Cheol Jeong  Hyun-Hee Cho  Jae-Woo Park 《Environmental Earth Sciences》2016,75(5):437

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Spectral-induced polarization characterization of rocks from the Handuk iron mine,South Korea     

S. W. Shin  Samgyu Park  D. B. Shin 《Environmental Earth Sciences》2016,75(9):827

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Leaching and redistribution of Cu and Pb due to simulated road runoff assessed by column leaching test,chemical analysis,and PHREEQC modeling     

Mohammad Nazrul Islam  Young-Tae Jo  Jeong-Hun Park 《Environmental Earth Sciences》2016,75(12):1041

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Hydraulic and Thermal Conductivities of Kaolin–Silica Mixtures under Different Consolidation Stresses     

Keunbo Park  Junhwan Lee  Hyung-Koo Yoon 《Marine Georesources & Geotechnology》2016,34(6):532-541

Stable backfill materials for the heat sensitive structures of buried power cables, hot water pipes, and gas pipelines are suggested to have low permeability and high heat transfer characteristics. The hydraulic and thermal conductivities of backfill materials or clay liners are important parameters in proper design and construction of geotechnical structures involved with heat transfers. In this study, to investigate the optimal natural backfill or liner materials, thermal and hydraulic conductivities of kaolin–silica mixtures examined based on the results from laboratory tests under different consolidation conditions. From the experiment results, the thermal conductivity increases while hydraulic conductivity decreases with increasing density during consolidation process. As a result, back-fill materials with high kaolin content under low consolidation stress were desirable materials for burial of heat sensitive structures.  相似文献   

Growth dynamics of the deep-water Asian eelgrass, <Emphasis Type="Italic">Zostera asiatica</Emphasis>, in the eastern coastal waters of Korea     

Jung-Im Park  Jong-Hyeob Kim  Su Hyun Park 《Ocean Science Journal》2016,51(4):613-625

Among the seagrasses that occur along the coast of Korea, Zostera asiatica inhabits the deepest depth; however, to date, there is limited information on its ecology. This study presents the first quantitative data on the seasonal growth dynamics of Z. asiatica in Korea. We measured seasonal growth and morphological characteristics, as well as environmental factors, including underwater irradiance, water temperature, salinity and nutrient concentrations of the water column and sediment pore water, bimonthly from July 2012 to May 2015. Underwater irradiance showed clear seasonal trends, increasing in the spring and summer and decreasing in the fall and winter, ranging from 2.4 ± 0.2 mol photons m^-2 d^-1 in November 2012 to 12.8 ± 1.3 mol photons m^-2 d^-1 in July 2014. Water temperature also followed a strong seasonal trend similar to underwater irradiance, ranging from 9.8 ± 0.1°C in January 2013 to 20.5 ± 0.2°C in September 2013. Nutrient availability fluctuated substantially, but there was no evidence of distinct seasonal variations. Shoot density, biomass, leaf productivity, and morphological characteristics of Z. asiatica exhibited significant seasonal variations: maximum values of these variables occurred in summer, and the minima were recorded in winter. Total shoot density was highest (218.8 ± 18.8 shoots m^-2) in July 2012 and lowest (106.3 ± 6.3 shoots m^-2) in January 2013. Total biomass ranged from 182.6 ± 16.9 g dry weight (DW) m^-2 in January 2015 to 310.9 ± 6.4 g DW m^-2 in July 2014.Areal leaf production was highest (4.9 ± 0.0 g DW m^-2 d^-1) in July 2012 and lowest (1.4 ± 0.2 g DW m^-2 d^-1) in January 2013. The optimum water temperature for the growth of Z. asiatica was between 16-19°C. Growth of Z. asiatica was more strongly correlated with underwater irradiance than water temperature, suggesting that light is the most important factor determining seasonality of Z. asiatica at the study site.  相似文献